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AMPED EFRC Publications 2009 – Present

  1. Niu, F.; Wang, D.; Williams, L. J.; Nayak, A.; Li, F.; Chen, X.; Troian-Gautier, L.; Huang, Q.; Liu, Y.; Brennaman, M. K.; Papanikolas, J. M.; Guo, L.; Shen, S.; Meyer, T. J. A Semiconductor-Mediator-Catalyst Artificial Photosynthetic System for Photoelectrochemical Water Oxidation. Chem. Eur. J. 2022, ASAP. https://doi.org/10.1002/chem.202102630
  2. Wang, D.; Fei, L.; Huang, Z.; Meyer, T. J. Design and characterization of surface molecular assemblies for the preparation of solar fuels. Chem. Phys. Rev. 2022, 3 (1), 011301. http://dx.doi.org/10.1063/5.0072430
  3. ​Gonell, S.; Assaf, E. A.; Lloret-Fillol, J.; Miller, A. J. M. An Iron Bis(carbene) Catalyst for Low Overpotential CO2 Electroreduction to CO: Mechanistic Insights from Kinetic Zone Diagrams, Spectroscopy, and Theory. ACS Catal. 2021, 11, 15212-15222. https://doi.org/10.1021/acscatal.1c04414
  4. ​​Mortelliti, M. J.; Huang, C; Atkin, J. M.; Dempsey, J. L. Mixed Tin-Titanium Oxides by Atomic Layer Deposition on Planar Substrates: Physical and Electronic Structure. Appl. Surf. Sci. 2022, 573, 151564. http://dx.doi.org/10.1016/j.apsusc.2021.151564
  5. Nhon, L.; Shan, B.; Taggart, A. D.; Wolfe, R. W.; Li, T.-T.; Klug, C. M.; Nayak, A.; Bullock, R. M.; Cahoon, J. F.; Meyer, T. J.; Schanze, K. S.; Reynolds, J. R. Influence of Surface and Structural Variations in Donor−Acceptor−Donor Sensitizers on Photoelectrocatalytic Water Splitting. ACS Appl. Mater. Interfaces. 2021, 13 (40), 47499-47510. http://dx.doi.org/10.1021/acsami.1c11879
  6. ​Zhao, Y.; Kim, S.; Eom, K. U.; Valandro, S. R.; Schanze, K. S. Polymer Chromophore-Catalyst Assembly for Photocatalytic CO2 Reduction. ACS Appl. Energy Mater. 2021, 4 (7), 7030-7039. https://doi.org/10.1021/acsaem.1c01100
  7. Mortelliti, M. J.; Wang, A. N.; Dempsey, J. L. Interfacial Electron Transfer through Ultrathin ALD TiOX Layers: A Comparative Study of TiO2/TiOX and SnO2/TiOX Core/Shell Nanocrystals. J. Phys. Chem. C. 2021, 125 (23), 12937-12959. http://dx.doi.org/10.1021/acs.jpcc.1c02428
  8. Rader Bowers, L. M.; Puodziukynaite, E.; Wang, L.; Morseth, Z. A.; Schanze, K. S.; Reynolds, J. R.; Papanikolas, J. M. It Is Good to Be Flexible: Energy Transport Facilitated by Conformational Fluctuations in Light-Harvesting Polymers. J. Phys. Chem. B. 2021, 125 (22) 5885-5896. https://doi.org/10.1021/acs.jpcb.1c00368
  9. Reilly, C. E.; Dillon, R. J.; Nayak, A.; Brogan, S.; Moot, T.; Brennaman, M. K.; Lopez, R.; Meyer, T. J.; Alibabaei, L. Dye-Sensitized Nonstoichiometric Strontium Titanate Core-Shell Photocathodes for Photoelectrosynthesis Applications. ACS Appl. Mater. Interfaces 2021, 13 (13) 15261-15269. https://doi.org/10.1021/acsami.1c00933​​
  10. Gonell, S.; Lloret-Fillol, J.; Miller, A. J. M. An Iron Pyridyl-Carbene Electrocatalyst for Low Overpotential CO2 Reduction to CO. ACS Catal. 2021, 11 (2), 615-626.​http://dx.doi.org/10.1021/acscatal.0c03798
  11. ​Bangle, R. E.; Mortelliti, M. J.; Troian-Gautier, L.; Dempsey, J. L.; Meyer, G. J. Tunneling and Thermally Activated Electron Transfer in Dye-Sensitized SnO2|TiO2 Core|Shell Nanostructures. J. Phys. Chem. C 2020, 124 (45), 25148-25159. http://dx.doi.org/10.1021/acs.jpcc.0c08200
  12. Taggart, A. D.; Evans, J. E.; Li, L.; Lee, K. J.; Dempsey, J. L.; Kanai, Y.; Cahoon, J. F. Enabling Aqueous NiO Photocathodes by Passivating Surface Sites That Facilitate Proton-Coupled Charge Transfer. ACS Appl. Energy Mater. 2020, 3 (11), 10702-10713. http://dx.doi.org/10.1021/acsaem.0c01751
  13. Nhon, L.; Taggart, A. D.; Moot, T.; Brennaman, M. K.; Jagadesan, P.; Schanze, K. S.; Cahoon, J. F.; Reynolds, J. R. Organic Chromophores Designed for Hole Injection into Wide-Band-Gap Metal Oxides for Solar Fuel Applications. Chem. Mater. 2020, 32 (19), 8158-8168. ​http://dx.doi.org/10.1021/acs.chemmater.0c01477
  14. Aramburu-Trošelj, B. M.; Bangle, R. E.; Meyer, G. J. Solvent influence on non-adiabatic interfacial electron transfer at conductive oxide electrolyte interfaces. J. Chem. Phys. 2020, 153 (13), 134702. http://dx.doi.org/10.1063/5.0023766
  15. Hu, K.; Sampaio, R. N.; Schneider, J.; Troian-Gautier, L.; Meyer, G. J. Perspectives on Dye Sensitization of Nanocrystalline Mesoporous Thin Films. J. Am. Chem. Soc. 2020, 142 (38), 16099-16116. , https://doi.org/10.1021/jacs.0c04886
  16. Dillon, R. J.; Pan, Z. X.; Jiang, J. L.; Winkel, R. W.; Papanikolas, J. M.; Schanze, K. S. Ultrafast Energy Transfer in Fully Conjugated Thiophene-Benzothiadiazole Capped Poly(Phenylene Ethynylene) Molecular Wires. J. Phys. Chem. C  2020, 124 (35), 18920-18929. http://dx.doi.org/10.1021/acs.jpcc.0c05808
  17. Wehlin, S. A. M.; Troian-Gautier, L.; Maurer, A. B.; Brennaman, M. K.; Meyer, G. J. Photophysical Characterization of New Osmium (II) Photocatalysts for Hydrohalic Acid Splitting. J. Chem. Phys. 2020, 153 (5), 054307. http://doi.org/10.1063/5.0014269
  18. Bangle, R. E.; Schneider, J.; Conroy, D. T.; Aramburu-Troselj, B. M.; Meyer, G. J. Kinetic Evidence that the Solvent Barrier for Electron Transfer is Absent in the Electric Double Layer. J. Am. Chem. Soc. 2020​, 142 (35), 14940-14946. http://dx.doi.org/10.1021/jacs.0c05226​ 
  19. Cordoba Hernandez, I. C.; Teitsworth, T. S.; Yang, M.; Cahoon, J. F.; Kavanagh, K. L. Abrupt degenerately-doped silicon nanowire tunnel junctions. Nanotechnology 2020, 31 (41), 415708. http://dx.doi.org/10.1088/1361-6528/ab95b3​
  20. Cheshire, T. P.; Brennaman, M. K.; Zigler, D. F.; Giokas, P. G. Moran, A. M.; Papanikolas, J. M.; Meyer, G. J.; Meyer, T. J.; Houle, F. A. Ultrafast Relaxations in Ruthenium Polypyridyl Chromophores Determined by Stochastic Kinetics Simulations. J. Phys. Chem. B. 2020, 124 ​(28), 5971-5985. http://dx.doi.org/10.1021/acs.jpcb.0c03110​
  21. Gonell, S.; Assaf, E. A.; Duffee, K.; Schauer, C. K.; Miller, A. J. M. Kinetics of the Trans Effect in Ruthenium Complexes Provide Insight into the Factors that Control Activity and Stability in CO2 Electroreduction. J. Am. Chem. Soc. 2020, 142 (19), 8980-8999. http://dx.doi.org/10.1021/jacs.0c02912
  22. McCullough, S. M.; Evans, J. M.; Moot, T.; Taggart, A.; Troian-Gautier, L.; Cahoon, J. F. Cation Effects in p-Type Dye Sensitized Solar Cells. ACS Appl. Energy Mater. 2020, 3 (2), 1496-1505. http://dx.doi.org/10.1021/acsaem.9b01955
  23. Badgurjar, D.; Shan, B.; Nayak, A.; Wu, L.; Chitta, R.; Meyer, T. J. Electron-Withdrawing BODIPY Dyes As Visible Light Absorber/Sensitizers on Semiconductor Oxide Surfaces. ACS Appl. Mater. Interfaces  2020, 12 (6), 7768-7776. http://dx.doi.org/10.1021/acsami.9b20167
  24. Bangle, R. E.; Schneider, J.; Piechota, E. J.; Troian-Gautier, L.; Meyer, G. J. Electron Transfer Reorganization Energies in the Electrode-Electrode Double Layer.  J. Am. Chem. Soc.  2020, 142 (2), 674-679. http://dx.doi.org/10.1021/jacs.9b11815
  25. Wang, D.; Wang, L.; Brady, M. D.; Dares, C. J.; Meyer, G. J.; Meyer, T. J.; Concepcion, J. J.  A Self-Assembled Chromophore/Catalyst Bilayer for Water Oxidation in a Dye-Sensitized Photoelectrosynthesis Cell.  J. Phys. Chem. C  2019, 123 (50), 30039-30045.  http://dx.doi.org/10.1021/acs.jpcc.9b07125
  26. Bangle, R. E.; Meyer, G. J.  Factors that Control the Direction of Excited State Electron Transfer at Dye-Sensitized Oxide Interfaces.  J. Phys. Chem. C  2019, 123 (42), 25967-25976.  http://dx.doi.org/10.1021/acs.jpcc.9b06755
  27. Wang, D.; Niu, F.; Mortelliti, M. J.; Sheridan, M. V.; Sherman, B. D.; Zhu, Y.; McBride, J. R.; Dempsey, J. L.; Shen, S.; Dares, C. J.; Li, F.; Meyer, T. J. A stable dye-sensitized photoelectrosynthesis cell mediated by a NiO overlayer for water oxidation. Proc. Natl. Acad. Sci. USA 2020, 117 (23), 12564-12571. http://dx.doi.org/10.1073/pnas.1821687116
  28. James, E. M.; Bennett, M. T.; Bangle, R. E.; Meyer, G. J. Electron Localization and Transport in SnO2/TiO2 Mesoporous Thin Films: Evidence for a
    SnO2/SnχTi1-χO2/TiO2 Structure. Langmuir 2019, 35 (39), 12694-12703. http://dx.doi.org/10.1021/acs.langmuir.9b02216
  29. Mortelliti, M. J.; Wang, A. N.; Dempsey, J. L. Atomic Layer Deposition of SnOx onto Mesoporous, Nanocrsytalline TiO2 and SnO2 Thin Films. Polyhedron 2019, 171, 433-447.  http://dx.doi.org/10.1016/j.poly.2019.07.021
  30. Schneider, J.; Bangle, R. E.; Swords, W. B.; Troian-Gautier, L.; Meyer, G. J. Determination of Proton-Coupled Electron Transfer Reorganization Energies with Application to Water Oxidation Catalysts. J. Am. Chem. Soc.  2019, 141 (25), 9758-9763. ​http://dx.doi.org/10.1021/jacs.9b01296
  31. Li, L.; Kanai, Y. Modeling Electron Injection at Semiconductor-Molecule Interfaces using First-Principles Dynamics Simulation: Effects of Nonadiabatic Coupling, Self-energy, and Surface Models. J. Phys. Chem. C  2019, 123 (21), 13295-13303. ​http://dx.doi.org/10.1021/acs.jpcc.9b01820
  32. Wang, D.; Sampaio, R. N.; Troian-Gautier, L.; Marquard, S. L.; Farnum, B. H.; Sherman, B. D.; Sheridan, M. V.; Dares, C. J.; Meyer, G. J.; Meyer, T. J.  A Molecular Photoelectrode for Water Oxidation Inspired by Photosystem II.  J. Am. Chem. Soc.  2019, 141 (19), 7926–7933.  http://dx.doi.org/10.1021/jacs.9b02548
  33. Gonell, S. G.; Massey, M. D.; Moseley, I. P.; Schauer, C. K.; Muckerman, J. T.; Miller, A. J. M.  Trans Effect in Electrocatalytic CO2 Reduction: Mechanistic Studies of Asymmetric Ruthenium Pyridyl-Carbene Catalysts. J. Am. Chem. Soc. 2019, 141 (16), 6658-6671. http://dx.doi.org/10.1021/jacs.9b01735
  34. Wang, D.; Wang, Y.; Brady, M. D.; Sheridan, M. V.; Sherman, B. D.; Farnum, B. H.; Liu, Y.; Marquard, S. L.; Meyer, G. J.; Dares, C. J.; Meyer, T. J. A Donor-Chromophore-Catalyst Assembly for Solar CO2 Reduction. Chem. Sci. 2019, 10, 4436-4444. http://dx.doi.org/10.1039/c8sc03316a
  35. Troian-Gautier, L.; Turlington, M. D.; Wehlin, S. A. M.; Maurer, A. B.; Brady, M. D.; Swords, W. B.; Meyer, G. J. Halide Photoredox Chemistry. Chem. Rev. 2019, 119 (7), 4628–4683. http://dx.doi.org/10.1021/acs.chemrev.8b00732
  36. Liu, Q.; Wang, D.; Sherman, B. D.; Marquard, S. L.; Eberhart, M. S.; Liu, M.; Li, C.; Meyer, T. J. Light-driven water oxidation by a dye-sensitized photoanode with a chromophore/catalyst assembly on a mesoporous double-shell electrode. J. Chem. Phys. 2019, 150 (4), 041727. http://dx.doi.org/10.1063/1.5048780
  37. Wong, J. C.; Li, L.; Kanai, Y. Size Dependence and Role of Decoherence in Hot Electron Relaxation within Fluorinated Silicon Quantum Dots: A First-Principles Study.  J. Phys. Chem. C  2018, 122 (51), 29526-29536. http://dx.doi.org/10.1021/acs.jpcc.8b08030
  38. Wang, Y.; Gonell, S. G.; Mathiyazhagan, U. R.; Liu, Y.; Wang, D.; Miller, A. J. M.; Meyer, T. J. Simultaneous Electrosynthesis of Syngas and an Aldehyde from CO2 and an Alcohol by Molecular Electrocatalysis. ACS Appl. Energy Mater. 2019, 2 (1), 97-101. http://dx.doi.org/10.1021/acsaem.8b01616
  39. Wu, L.; Eberhart, M.; Nayak, A.; Brennaman, M. K.; Shan, B.; Meyer, T. J. A Molecular Silane-Derivatized Ru(II) Catalyst for Photoelectrochemical Water Oxidation. J. Am. Chem. Soc. 2018, 140 (44), 15062-15069. http://dx.doi.org/10.1021/jacs.8b10132
  40. Sampaio, R. N.; Troian-Gautier, L.; Meyer, G. J. A Charge-Separated State that Lives for Almost a Second at a Conductive Metal Oxide Interface. Angew. Chem. Int. Ed. 2018, 57 (47), 15390-15394. http://dx.doi.org/10.1002/anie.201807627​.​
  41. Gonell, S. G.; Miller, A. J. M., Carbon Dioxide Electroreduction Catalyzed by Organometallic Complexes. In Advances in Organometallic Chemistry, Vol 70, First ed., Pérez, P. J.; Stone, F. G. A.; West, R., Eds., Academic Press, 2018, Vol. 70, pp. 1-69. https://dx.doi.org/10.1016/bs.adomc.2018.07.001
  42. Brady, M. D.; Troian-Gautier, L.; Sampaio, R. N.; Motley, T. C.; Meyer, G. J. Optimization of Photocatalyst Excited- and Ground-State Reduction Potentials for Dye-Sensitized HBr Splitting. ACS Appl. Mater. Interfaces. 2018, 10 (37), 31312-31323. http://dx.doi.org/10.1021/acsami.8b09134
  43. Wang, D.; Eberhart, M. S.; Sheridan, M. V.; Hu, K.; Sherman, B. D.; Nayak, A.; Wang, Y.; Marquard, S. L.; Dares, C. J.; Meyer, T. J. Stabilized Photoanodes for Water Oxidation. Integration of Organic Dyes, Water Oxidation Catalysts, and Electron-Transfer Mediators. Proc. Natl. Acad. Sci. USA 2018, 115 (34), 8523-8528. http://dx.doi.org/10.1073/pnas.1802903115
  44. Eom, Y. K.; Nhon, L.; Leem, G.; Sherman, B. D.; Wang, D.; Troian-Gautier, L.; Kim, S.; Kim, J.; Meyer, T. J.; Reynolds, J. R.; Schanze, K. S. Visible-Light Driven Photocatalytic Water Oxidation by a π-Conjugated Donor-Acceptor-Donor Chromophore/Catalyst Assembly. ACS Energy Lett. 2018, 3 (9), 2114-2119. http://dx.doi.org/10.1021/acsenergylett.8b01020
  45. Eberhart, M. S.; Bowers, L. M. R.; Shan, B.; Troian-Gautier, L.; Brennaman, M. K.; Papanikolas, J. M.; Meyer, T. J. Completing a Charge Transport Chain for Artificial Photosynthesis. J. Am. Chem. Soc. 2018, 140 (31), 9823-9826. http://dx.doi.org/10.1021/jacs.8b06740
  46. Dongare, P.; Wang, Y.; Bass, D. M.; Meyer, T. J. Catalytic Interconversion of the Quinone/Hydroquinone Couple by a Surface-Bound Os(III/II) Polypyridyl Couple. J. Phys. Chem. C 2018, 122 (28), 16189-16194. http://dx.doi.org/10.1021/acs.jpcc.8b04920
  47. Raber, M. M.; Brady, M. D.; Troian-Gautier, L.; Dickenson, J. C.; Marquard, S. L.; Hyde, J. T.; Lopez, S. J.; Meyer, G. J.; Meyer, T. J.; Harrison, D. P. Fundamental Factors Impacting the Stability of Phosphonate-Derivatized adsorbed-Ru(III) Chromophore Sensitizers. ACS Appl. Mater. Interfaces 2018, 10 (26), 22821–22833. http://dx.doi.org/10.1021/acsami.8b04587
  48. Brennaman, M. K.; Gish, M. K.; Alibabaei, L.; Norris, M. R.; Binstead, R. A.; Nayak, A.; Lapides, A. M.; Song, W.; Brown, R. J.; Concepcion, J. J.; Templeton, J. L.; Papanikolas, J. M.; Meyer, T. J. Pathways following Electron Injection: Medium Effects and Cross-Surface Electron Transfer in a Ruthenium-Based, Chromophore-Catalyst Assembly on TiO2. J. Phys. Chem. C 2018, 122 (24), 13017-13026. http://dx.doi.org/10.1021/acs.jpcc.8b04837
  49. Piechota, E. J.; Troian-Gautier, L.; Sampaio, R. N.; Brennaman, M. K.; Hu, K.; Berlinguette, C. P.; Meyer, G. J. Optical intramolecular electron transfer in opposite directions through the same bridge that follows different pathways. J. Am. Chem. Soc. 2018, 140 (23), 7176-7186. http://dx.doi.org/10.1021/jacs.8b02715
  50. Li, L.; Kanai, Y. Dependence of hot electron transfer on surface coverage and adsorbate species at semiconductor-molecule interfaces. Phys. Chem. Chem. Phys. 2018, 20, 12986-12991. http://dx.doi.org/10.1039/c7cp07247c
  51. Kurtz, D. A.; Brereton, K. R.; Ruoff, K. P.; Tang, H. M.; Felton, G. A. N.; Miller, A. J. M.; Dempsey, J. L. Bathochromic Shifts in Rhenium Carbonyl Dyes Induced through Destabilization of Occupied Orbitals. Inorg. Chem. 2018, 57 (9), 5389-5399. http://dx.doi.org/10.1021/acs.inorgchem.8b00360
  52. Call, R. W.; Brogan, S.; Alibabaei, L.; Lopez, R. Impedance spectroscopy study of SrTiO3 pulse laser deposited photoelectrodes. Thin Solid Films 2018, 655, 27-33. http://dx.doi.org/10.1016/j.tsf.2018.04.002
  53. Li, G.; Brady, M. D.; Meyer, G. J. Visible Light Driven Bromide Oxidation and Ligand Substitution Photochemistry of a Ru Diimine Complex. J. Am. Chem. Soc. 2018, 140 (16), 5447-5466. http://dx.doi.org/10.1021/jacs.8b00944
  54. Troian-Gautier, L.; DiMarco, B. N.; Sampaio, R. N.; Marquard, S. L.; Meyer, G. J. Evidence that ∆S‡ Controls Interfacial Electron Transfer Dynamics from Anatase TiO2 to Molecular Acceptors. J. Am. Chem. Soc. 2018, 140 (8), 3019-3029. http://dx.doi.org/10.1021/jacs.7b13243
  55. Sheridan, M. V.; Wang, Y.; Wang, D.; Troian-Gautier, L.; Dares, C. J.; Sherman, B. D.; Meyer, T. J. Light-Driven Water Splitting Mediated by Photogenerated Bromine. Angew. Chem. Int. Ed. 2018, 57 (13), 3449-3453. http://dx.doi.org/10.1002/anie.201708879
  56. Nayak, A.; Hu, K.; Roy, S.; Brennaman, M. K.; Shan, B.; Meyer, G. J.; Meyer, T. J. Synthesis and Photophysical Properties of a Covalently Linked, Porphyrin Chromophore-Ru(II) Water Oxidation Catalyst Assembly on SnO2 Electrodes. J. Phys. Chem. C 2018, 122 (25), 13455-13461. http://dx.doi.org/10.1021/acs.jpcc.7b11711
  57. James, E. M.; Barr, T. J.; Meyer, G. J. Evidence for an Electronic State at the Interface between the SnO2 Core and the TiO2 Shell in Mesoporous SnO2/TiO2 Thin Films. ACS Appl. Energy Mater. 2018, 1 (2), 859-867. http://dx.doi.org/10.1021/acsaem.7b00274
  58. Leem, G.; Black, H. T.; Shan, B.; Bantang, J. P. O.; Meyer, T. J.; Reynolds, J. R.; Schanze, K. S. Photocathode Chromophore–Catalyst Assembly via Layer-By-Layer Deposition of a Low Band-Gap Isoindigo Conjugated Polyelectrolyte. ACS Appl. Energy Mater. 2018, 1 (1), 62-67. http://dx.doi.org/10.1021/acsaem.7b00223
  59. Wang, Y.; Wang, D.; Dares, C. J.; Marquard, S. L.; Sheridan, M. V.; Meyer, T. J. CO2 reduction to acetate in mixtures of ultrasmall (Cu)n,(Ag)m bimetallic nanoparticles. Proc. Natl. Acad. Sci. USA 2018, 115 (2), 278-283. http://dx.doi.org/10.1073/pnas.1713962115
  60. Bangle, R.; Sampaio, R. N.; Troian-Gautier, L.; Meyer, G. J. Surface Grafting of Ru(II) Diazonium-Based Sensitizers on Metal Oxides Enhances Alkaline Stability for Solar Energy Conversion. ACS Appl. Mater. Interfaces 2018, 10 (3), 3121-3132. http://dx.doi.org/10.1021/acsami.7b16641
  61. Leem, G.; Sherman, B. D.; Schanze, K. S. Polymer-based chromophore-catalyst assemblies for solar energy conversion. Nano Converg. 2017, 4 (1), 37. http://dx.doi.org/10.1186/s40580-017-0132-z
  62. Hu, K.; Sampaio, R. N.; Marquard, S. L.; Brennaman, M. K.; Tamaki, Y.; Meyer, T. J.; Meyer, G. J. A High-Valent Metal-Oxo Species Produced by Photoinduced One-Electron, Two-Proton Transfer Reactivity. Inorg. Chem. 2018, 57 (1), 486-494. http://dx.doi.org/10.1021/acs.inorgchem.7b02758
  63. Wang, D.; Marquard, S. L.; Troian-Gautier, L.; Sheridan, M. V.; Sherman, B. D.; Wang, Y.; Eberhart, M. S.; Farnum, B. H.; Dares, C. J.; Meyer, T. J. Interfacial Deposition of Ru(II) Bipyridine-Dicarboxylate Complexes by Ligand Substitution for Applications in Water Oxidation Catalysis. J. Am. Chem. Soc. 2018, 140 (2), 719-726. http://dx.doi.org/10.1021/jacs.7b10809
  64. Han, Y.; Dillon, R. J.; Flynn, C. J.; Rountree, E. S.; Alibabaei, L.; Cahoon, J. F.; Papanikolas, J. M.; Dempsey, J. L. Interfacial Electron Transfer Yields in Dye-Sensitized NiO Photocathodes Correlated to Excited-State Dipole Orientation of Ruthenium Chromophores. Can. J. Chem. 2018, 96 (9), 865-874. http://dx.doi.org/10.1139/cjc-2017-0359
  65. Motley, T. C.; Troian-Gautier, L.; Brennaman, M. K.; Meyer, G. J. Excited-State Decay Pathways of Tris(bidentate) Cyclometalated Ruthenium(II) Compounds. Inorg. Chem. 2017, 56 (21), 13579-13592. http://dx.doi.org/10.1021/acs.inorgchem.7b02321
  66. Brady, M. D.; Sampaio, R. N.; Wang, D.; Meyer, T. J.; Meyer, G. J. Dye-Sensitized Hydrobromic Acid Splitting for Hydrogen Solar Fuel Production. J. Am. Chem. Soc. 2017, 139 (44), 15612–15615. http://dx.doi.org/10.1021/jacs.7b09367
  67. Alibabaei, L.; Dillon, R. J.; Reilly, C. E.; Brennaman, M. K.; Wee, K.-R.; Marquard, S. L.; Papanikolas, J. M.; Meyer, T. J. Chromophore-Catalyst Assembly for Water Oxidation Prepared by Atomic Layer Deposition. ACS Appl. Mater. Interfaces 2017, 9 (44), 39018–39026. http://dx.doi.org/10.1021/acsami.7b11905
  68. Eberhart, M. S.; Wang, D.; Sampaio, R. N.; Marquard, S. L.; Shan, B.; Brennaman, M. K.; Meyer, G. J.; Dares, C.; Meyer, T. J. Water Photo-Oxidation Initiated by Surface-Bound Organic Chromophores. J. Am. Chem. Soc. 2017, 139 (45), 16248-16255. http://dx.doi.org/10.1021/jacs.7b08317
  69. Alibabaei, L.; Brennaman, M. K.; Meyer, T. J., Light-Driven Water-Splitting in the Dye Sensitized Photoelectrosynthesis Cell. In Molecular Devices for Solar Energy Conversion and Storage, First ed.; Tian, H.; Boschloo, G.; Hagfeldt, A., Eds. Springer: Singapore, 2018; pp. 229-257. http://dx.doi.org/10.1007/978-981-10-5924-7_6
  70. Meyer, T. J.; Sheridan, M. V.; Sherman, B. D. Mechanisms of molecular water oxidation in solution and on oxide surfaces. Chem. Soc. Rev. 2017, 46 (20), 6148-6169. http://dx.doi.org/10.1039/c7cs00465f
  71. Shan, B.; Sherman, B. D.; Klug, C. M.; Nayak, A.; Marquard, S. L.; Liu, Q.; Bullock, R. M.; Meyer, T. J. Modulating Hole Transport in Multilayered Photocathodes with Derivatized p-Type Nickel Oxide and Molecular Assemblies for Solar-Driven Water Splitting. J. Phys. Chem. Lett. 2017, 8 (18), 4374-4379. http://dx.doi.org/10.1021/acs.jpclett.7b01911
  72. Wang, D.; Sheridan, M. V.; Shan, B.; Farnum, B. H.; Marquard, S. L.; Sherman, B. D.; Eberhart, M. S.; Nayak, A.; Dares, C. J.; Das, A. K.; Bullock, R. M.; Meyer, T. J. Layer-by-Layer Molecular Assemblies for Dye-Sensitized Photoelectrosynthesis Cells Prepared by Atomic Layer Deposition. J. Am. Chem. Soc. 2017, 139 (41), 14518-14525. http://dx.doi.org/10.1021/jacs.7b07216
  73. Dillon, R. J.; Alibabaei, L.; Meyer, T. J.; Papanikolas, J. M. Enabling Efficient Creation of Long-Lived Charge-Separation on Dye-Sensitized NiO Photocathodes. ACS Appl. Mater. Interfaces 2017, 9 (32), 26786-26796. http://dx.doi.org/10.1021/acsami.7b05856
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  154. Alibabaei, L.; Farnum, B. H.; Kalanyan, B.; Brennaman, M. K.; Losego, M. D.; Parsons, G. N.; Meyer, T. J. Atomic Layer Deposition of TiO2 on Mesoporous nanoITO: Conductive Core-Shell Photoanodes for Dye-Sensitized Solar Cells. Nano Lett. 2014, 14 (6), 3255-3261. http://dx.doi.org/10.1021/nl5006433
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  163. Zanoni, K. P.; Kariyazaki, B. K.; Ito, A.; Brennaman, M. K.; Meyer, T. J.; Murakami Iha, N. Y. Blue-Green Iridium(III) Emitter and Comprehensive Photophysical Elucidation of Heteroleptic Cyclometalated Iridium(III) Complexes. Inorg. Chem. 2014, 53 (8), 4089-4099. http://dx.doi.org/10.1021/ic500070s
  164. Fang, Z.; Keinan, S.; Alibabaei, L.; Luo, H.; Ito, A.; Meyer, T. J. Controlled Electropolymerization of Ruthenium(II) Vinylbipyridyl Complexes in Mesoporous Nanoparticle Films of TiO2. Angew. Chem. Int. Ed. 2014, 126 (19), 4872-4876. http://dx.doi.org/10.1002/ange.201402309
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  169. Farnum, B. H.; Morseth, Z. A.; Lapides, A. M.; Rieth, A. J.; Hoertz, P. G.; Brennaman, M. K.; Papanikolas, J. M.; Meyer, T. J. Photoinduced Interfacial Electron Transfer within a Mesoporous Transparent Conducting Oxide Film. J. Am. Chem. Soc. 2014, 136 (6), 2208-2211. http://dx.doi.org/10.1021/ja4106418
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  171. Puodziukynaite, E.; Wang, L.; Schanze, K. S.; Papanikolas, J. M.; Reynolds, J. R. Poly(fluorene-co-thiophene)-based ionic transition-metal complex polymers for solar energy harvesting and storage applications. Polym. Chem. 2014, 5 (7), 2363-2369. http://dx.doi.org/10.1039/c3py01582c
  172. Zhang, S.; Kang, P.; Meyer, T. J. Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate. J. Am. Chem. Soc. 2014, 136 (5), 1734-1737. http://dx.doi.org/10.1021/ja4113885
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  175. Chen, Z.; Grumstrup, E. M.; Gilligan, A. T.; Papanikolas, J. M.; Schanze, K. S. Light-Harvesting Polymers: Ultrafast Energy Transfer in Polystyrene-Based Arrays of π-Conjugated Chromophores. J. Phys. Chem. B 2014, 118 (1), 372-378. http://dx.doi.org/10.1021/jp411565p
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  180. Kent, C. A.; Liu, D.; Ito, A.; Zhang, T.; Brennaman, M. K.; Meyer, T. J.; Lin, W. Rapid energy transfer in non-porous metal–organic frameworks with caged Ru(bpy)32+ chromophores: oxygen trapping and luminescence quenching. J. Mater. Chem. A 2013, 1 (47), 14982-14989. http://dx.doi.org/10.1039/c3ta14009a
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  187. Fang, Z.; Ito, A.; Stuart, A. C.; Luo, H.; Chen, Z.; Vinodgopal, K.; You, W.; Meyer, T. J.; Taylor, D. K. Soluble Reduced Graphene Oxide Sheets Grafted with Polypyridylruthenium-Derivatized Polystyrene Brushes as Light Harvesting Antenna for Photovoltaic Applications. ACS Nano 2013, 7 (9), 7992-8002. http://dx.doi.org/10.1021/nn403079z
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  192. Song, W.; Ito, A.; Binstead, R. A.; Hanson, K.; Luo, H.; Brennaman, M. K.; Concepcion, J. J.; Meyer, T. J. Accumulation of Multiple Oxidative Equivalents at a Single Site by Cross-Surface Electron Transfer on TiO2. J. Am. Chem. Soc. 2013, 135 (31), 11587-11594. http://dx.doi.org/10.1021/ja4032538
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  198. Grumstrup, E. M.; Chen, Z.; Vary, R. P.; Moran, A. M.; Schanze, K. S.; Papanikolas, J. M. Frequency Modulated Femtosecond Stimulated Raman Spectroscopy of Ultrafast Energy Transfer in a Donor-Acceptor Copolymer. J. Phys. Chem. B 2013, 117 (27), 8245-8255. http://dx.doi.org/10.1021/jp404498u
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  200. Chen, Z.; Glasson, C. R.; Holland, P. L.; Meyer, T. J. Electrogenerated polypyridyl ruthenium hydride and ligand activation for water reduction to hydrogen and acetone to iso-propanol. Phys. Chem. Chem. Phys. 2013, 15 (24), 9503-9507. http://dx.doi.org/10.1039/c3cp51946e
  201. Brennaman, M. K.; Fleming, C. N.; Slate, C. A.; Serron, S. A.; Bettis, S. E.; Erickson, B. W.; Papanikolas, J. M.; Meyer, T. J. Distance Dependence of Intrahelix RuII* to OsII Polypyridyl Excited-State Energy Transfer in Oligoproline Assemblies. J. Phys. Chem. B 2013, 117 (21), 6352-6363. http://dx.doi.org/10.1021/jp400312f
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  203. Le, K.; Chand, L. B.; Griffin, C.; Williams, A. L.; Taylor, D. K. Paraphenylene dimers with diphenylamine donor groups: synthesis and photophysics. Tetrahedron Lett. 2013, 54 (24), 3097-3100. http://dx.doi.org/10.1016/j.tetlet.2013.03.141
  204. Peng, Q.; Kalanyan, B.; Hoertz, P. G.; Miller, A.; Kim, D. H.; Hanson, K.; Alibabaei, L.; Liu, J.; Meyer, T. J.; Parsons, G. N.; Glass, J. T. Solution-Processed, Antimony-Doped Tin Oxide Colloid Films Enable High-Performance TiO2 Photoanodes for Water Splitting. Nano Lett. 2013, 13 (4), 1481-1488. http://dx.doi.org/10.1021/nl3045525
  205. Ok, M. R.; Ghosh, R.; Brennaman, M. K.; Lopez, R.; Meyer, T. J.; Samulski, E. T. Surface Patterning of Mesoporous Niobium Oxide Films for Solar Energy Conversion. ACS Appl. Mater. Interfaces 2013, 5 (8), 3469-3474. http://dx.doi.org/10.1021/am400598u
  206. Ma, D.; Bettis, S. E.; Hanson, K.; Minakova, M.; Alibabaei, L.; Fondrie, W.; Ryan, D. M.; Papoian, G. A.; Meyer, T. J.; Waters, M. L.; Papanikolas, J. M. Interfacial Energy Conversion in RuII Polypyridyl-Derivatized Oligoproline Assemblies on TiO2. J. Am. Chem. Soc. 2013, 135 (14), 5250-5253. http://dx.doi.org/10.1021/ja312143h
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  208. Ito, A.; Stewart, D. J.; Knight, T. E.; Fang, Z.; Brennaman, M. K.; Meyer, T. J. Excited-State Dynamics in Rigid Media: Evidence for Long-Range Energy Transfer. J. Phys. Chem. B 2013, 117 (12), 3428-3438. http://dx.doi.org/10.1021/jp400514r
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  210. Moonshiram, D.; Purohit, V.; Concepcion, J. J.; Meyer, T. J.; Pushkar, Y. Mechanism of Catalytic Water Oxidation by the Ruthenium Blue Dimer Catalyst: Comparative Study in D2O versus H2O. Materials 2013, 6 (2), 392-409. http://dx.doi.org/10.3390/ma6020392
  211. Chen, Z. F.; Kang, P.; Zhang, M.-T.; Stoner, B. R.; Meyer, T. J. Cu(II)/Cu(0) electrocatalyzed CO2 and H2O splitting. Energy Environ. Sci. 2013, 6 (3), 813-817. http://dx.doi.org/10.1039/C3ee24487c
  212. Alibabaei, L.; Luo, H. L.; House, R. L.; Hoertz, P. G.; Lopez, R.; Meyer, T. J. Applications of metal oxide materials in dye sensitized photoelectrosynthesis cells for making solar fuels: let the molecules do the work. J. Mater. Chem. A 2013, 1 (13), 4133-4145. http://dx.doi.org/10.1039/C2ta00935h
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  297. Song, W. J.; Chen, Z. F.; Brennaman, M. K.; Concepcion, J. J.; Patrocinio, A. O. T.; Iha, N. Y. M.; Meyer, T. J. Making solar fuels by artificial photosynthesis. Pure Appl. Chem. 2011, 83 (4), 749-768. http://dx.doi.org/10.1351/Pac-Con-10-11-09
  298. Price, S. C.; Stuart, A. C.; Yang, L.; Zhou, H.; You, W. Fluorine Substituted Conjugated Polymer of Medium Band Gap Yields 7% Efficiency in Polymer-Fullerene Solar Cells. J. Am. Chem. Soc. 2011, 133 (12), 4625-4631. http://dx.doi.org/10.1021/ja1112595
  299. Zhou, H.; Yang, L.; Stuart, A. C.; Price, S. C.; Liu, S.; You, W. Development of Fluorinated Benzothiadiazole as a Structural Unit for a Polymer Solar Cell of 7% Efficiency. Angew. Chem. Int. Ed. 2011, 50 (13), 2995-2998. http://dx.doi.org/10.1002/anie.201005451
  300. Huang, Y.; Zhong, A.-G.; Yang, Q.; Liu, S. Origin of anomeric effect: A density functional steric analysis. J. Chem. Phys. 2011, 134 (8), 084103. http://dx.doi.org/10.1063/1.3555760
  301. Brennaman, M. K.; Patrocinio, A. O. T.; Song, W.; Jurss, J. W.; Concepcion, J. J.; Hoertz, P. G.; Traub, M. C.; Iha, N. Y. M.; Meyer, T. J. Interfacial Electron Transfer Dynamics Following Laser Flash Photolysis of [Ru(bpy)2((4,4′-PO3H2)2bpy)]2+ in TiO2 Nanoparticle Films in Aqueous Environments. ChemSusChem. 2011, 4 (2), 216-227. http://dx.doi.org/10.1002/cssc.201000356
  302. Gagliardi, C. J.; Jurss, J. W.; Thorp, H. H.; Meyer, T. J. Surface Activation of Electrocatalysis at Oxide Electrodes. Concerted Electron-Proton Transfer. Inorg. Chem. 2011, 50 (6), 2076-2078. http://dx.doi.org/10.1021/ic102524f
  303. Burger, S. K.; Liu, S.; Ayers, P. W. Practical Calculation of Molecular Acidity with the Aid of a Reference Molecule. J. Phys. Chem. A 2011, 115 (7), 1293-1304. http://dx.doi.org/10.1021/jp111148q
  304. Xie, Z.; Wang, C.; deKrafft, K. E.; Lin, W. Highly Stable and Porous Cross-Linked Polymers for Efficient Photocatalysis. J. Am. Chem. Soc. 2011, 133 (7), 2056-2059. http://dx.doi.org/10.1021/ja109166b
  305. Paul, A.; Hull, J. F.; Norris, M. R.; Chen, Z.; Ess, D. H.; Concepcion, J. J.; Meyer, T. J. Multiple Pathways for Benzyl Alcohol Oxidation by RuV=O3+ and RuIV=O2+. Inorg. Chem. 2011, 50 (4), 1167-1169. http://dx.doi.org/10.1021/ic1024923
  306. Subotnik, J. E.; Shenvi, N. A new approach to decoherence and momentum rescaling in the surface hopping algorithm. J. Chem. Phys. 2011, 134 (2), 024105. http://dx.doi.org/10.1063/1.3506779
  307. Miller, S. A.; Stuart, A. C.; Womick, J. M.; Zhou, H. X.; You, W.; Moran, A. M. Excited-State Photophysics in a Low Band Gap Polymer with High Photovoltaic Efficiency. J. Phys. Chem. C 2011, 115 (5), 2371-2380. http://dx.doi.org/10.1021/Jp108534d
  308. Tsuchiya, T.; Whitten, J. L. Theoretical Study of the Molecular and Electronic Structures of TiO4H4, Ti2O7H6, and Ti2O6H4. J. Phys. Chem. C 2011, 115 (5), 1635-1642. http://dx.doi.org/10.1021/jp109393x
  309. Ess, D. H.; Johnson, E. R.; Hu, X.; Yang, W. Singlet-Triplet Energy Gaps for Diradicals from Fractional-Spin Density-Functional Theory. J. Phys. Chem. A 2011, 115 (1), 76-83. http://dx.doi.org/10.1021/jp109280y
  310. Meyer, T. J.; Papanikolas, J. M.; Heyer, C. M. Solar Fuels and Next Generation Photovoltaics: The UNC-CH Energy Frontier Research Center. Catal. Lett. 2011, 141 (1), 1-7. http://dx.doi.org/10.1007/s10562-010-0495-9
  311. Chen, Z.; Concepcion, J. J.; Luo, H.; Hull, J. F.; Paul, A.; Meyer, T. J. Nonaqueous Catalytic Water Oxidation. J. Am. Chem. Soc. 2010, 132 (50), 17670-17673. http://dx.doi.org/10.1021/ja107347n
  312. Ess, D. H.; Liu, S.; De Proft, F. Density Functional Steric Analysis of Linear and Branched Alkanes. J. Phys. Chem. A 2010, 114 (49), 12952-12957. http://dx.doi.org/10.1021/jp108577g
  313. Shenvi, N.; Izmaylov, A. F. Active-Space N-Representability Constraints for Variational Two-Particle Reduced Density Matrix Calculations. Phys. Rev. Lett. 2010, 105 (21), 213003. http://dx.doi.org/10.1103/PhysRevLett.105.213003
  314. Chen, Z.; Concepcion, J. J.; Meyer, T. J. Rapid catalytic water oxidation by a single site, Ru carbene catalyst. Dalton Trans. 2011, 40 (15), 3789-3792. http://dx.doi.org/10.1039/c0dt01178a
  315. Ess, D. H.; Schauer, C. K.; Meyer, T. J. Theory of Hydride-Proton Transfer (HPT) Carbonyl Reduction by [OsIII(tpy)(Cl)(NH=CHCH3)(NSAr)]. J. Am. Chem. Soc. 2010, 132 (46), 16318-16320. http://dx.doi.org/10.1021/ja106403e
  316. Singh-Rachford, T. N.; Nayak, A.; Muro-Small, M. L.; Goeb, S.; Therien, M. J.; Castellano, F. N. Supermolecular-Chromophore-Sensitized Near-Infrared-to-Visible Photon Upconversion. J. Am. Chem. Soc. 2010, 132 (40), 14203-14211. http://dx.doi.org/10.1021/ja105510k
  317. Kent, C. A.; Mehl, B. P.; Ma, L.; Papanikolas, J. M.; Meyer, T. J.; Lin, W. Energy Transfer Dynamics in Metal-Organic Frameworks. J. Am. Chem. Soc. 2010, 132 (37), 12767-12769. http://dx.doi.org/10.1021/ja102804s
  318. Hoertz, P. G.; Goldstein, A.; Donley, C.; Meyer, T. J. Using the Voids. Evidence for an Antenna Effect in Dye-Sensitized Mesoporous TiO2 Thin Films. J. Phys. Chem. B 2010, 114 (45), 14772-14777. http://dx.doi.org/10.1021/jp103867j
  319. Hoertz, P. G.; Chen, Z.; Kent, C. A.; Meyer, T. J. Application of High Surface Area Tin-Doped Indium Oxide Nanoparticle Films as Transparent Conducting Electrodes. Inorg. Chem. 2010, 49 (18), 8179-8181. http://dx.doi.org/10.1021/ic100719r
  320. Chen, Z.; Concepcion, J. J.; Hull, J. F.; Hoertz, P. G.; Meyer, T. J. Catalytic water oxidation on derivatized nanoITO. Dalton Trans. 2010, 39 (30), 6950-6952. http://dx.doi.org/10.1039/c0dt00362j
  321. Chen, Z.; Concepcion, J. J.; Hu, X.; Yang, W.; Hoertz, P. G.; Meyer, T. J. Concerted O atom-proton transfer in the O–O bond forming step in water oxidation. Proc. Natl. Acad. Sci. USA 2010, 107 (16), 7225-7229. http://dx.doi.org/10.1073/pnas.1001132107
  322. Liu, S.; Hu, H.; Pedersen, L. G. Steric, Quantum, and Electrostatic Effects on SN2 Reaction Barriers in Gas Phase. J. Phys. Chem. A 2010, 114 (18), 5913-5918. http://dx.doi.org/10.1021/jp101329f
  323. Jurss, J. W.; Concepcion, J. C.; Norris, M. R.; Templeton, J. L.; Meyer, T. J. Surface Catalysis of Water Oxidation by the Blue Ruthenium Dimer. Inorg. Chem. 2010, 49 (9), 3980-3982. http://dx.doi.org/10.1021/ic100469x
  324. Gagliardi, C. J.; Westlake, B. C.; Kent, C. A.; Paul, J. J.; Papanikolas, J. M.; Meyer, T. J. Integrating proton coupled electron transfer (PCET) and excited states. Coord. Chem. Rev. 2010, 254 (21-22), 2459-2471. http://dx.doi.org/10.1016/j.ccr.2010.03.001
  325. Williams, S. S.; Retterer, S.; Lopez, R.; Ruiz, R.; Samulski, E. T.; DeSimone, J. M. High-Resolution PFPE-based Molding Techniques for Nanofabrication of High-Pattern Density, Sub-20 nm Features: A Fundamental Materials Approach. Nano Lett. 2010, 10 (4), 1421-1428. http://dx.doi.org/10.1021/nl100326q
  326. Hampton, M. J.; Templeton, J. L.; DeSimone, J. M. Direct Patterning of CdSe Quantum Dots into Sub-100 nm Structures. Langmuir 2010, 26 (5), 3012-3015. http://dx.doi.org/10.1021/la904787k
  327. Miller, S. A.; Moran, A. M. Nonlinear Optical Detection of Electron Transfer Adiabaticity in Metal Polypyridyl Complexes. J. Phys. Chem. A 2010, 114 (5), 2117-2126. http://dx.doi.org/10.1021/jp9092145
  328. Concepcion, J. J.; Tsai, M.-K.; Muckerman, J. T.; Meyer, T. J. Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts. J. Am. Chem. Soc. 2010, 132 (5), 1545-1557. http://dx.doi.org/10.1021/ja904906v
  329. Concepcion, J. J.; Jurss, J. W.; Norris, M. R.; Chen, Z.; Templeton, J. L.; Meyer, T. J. Catalytic Water Oxidation by Single-Site Ruthenium Catalysts. Inorg. Chem. 2010, 49 (4), 1277-1279. http://dx.doi.org/10.1021/ic901437e
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